Mix Mexican All Spice in a container or bowl and set aside.
Brown ground beef to your preference while adding lots of spice (I leave the beef a little on the rare side myself since it's cooking further in the crock pot.) While you are browning meat, open and drain all water from beans and corn and add to a 4 qt. or larger crock pot, turned on high. When meat is done, drain most of grease but leave a little bit for flavor and consistency of chili. Finally, combine all ingredients together, cover and cook on high for 5 hours or low for 8 hours.
When serving chili you can add some shredded cheddar cheese on top and sour cream, depending on your preference.